Wed. Jan 25th, 2023
    Francium

    Francium is a chemical element with the symbol Fr and atomic number 87

    Francium, known for a time as eka-cesium and actinium K, is the chemical element with atomic number 87, symbol Fr. It is a radioactive alkali metal with atomic mass 223. It was named in tribute to France by Marguerite Perey in 1939.

    It is the least stable of the elements with an atomic number less than 106 (seaborgium). As an alkali, its properties are close to those of cesium, with which it precipitates in the form of several salts. This property can be used to isolate it. Francium has the lowest electronegativity of all the elements.

    The francium in the form of chunks has never been seen. When viewed from the general characteristics of the other elements in the column on the periodic table, it is assumed that francium is a very reactive metal. Getting a sample was nearly impossible, as the extreme heat of decay (longest half-life of the isotope is only 22 minutes) would immediately vaporize whenever any amount of the element could be seen.

    Physical properties

    The physical properties are essentially estimates that have been determined by extrapolating the properties of the alkali metals or by model calculations. Investigations on compact samples of the metal or its compounds are due to the small quantities that can be produced (few attograms , ~ 10,000 atoms) and the high level of radioactivity (activity is about 2 million times higher than that of the same amount of 238 Pu (plutonium): visible quantities would evaporate immediately) hardly possible.

    Use of francium

    Due to its low half-life, francium has no commercial applications. On the other hand, measurements of transitions between atomic energy levels have been carried out thanks to its relatively simple electronic structure.

    It has been used in the field of research, chemistry and also in the atomic structure. It is used for diagnostics for curing cancers.

    Preclinical in vivo models have been of significant benefit in evaluating innovative methods of detecting tumors and novel therapeutic intervention approaches for potential use in treating human cancers.

    It is also used in many spectroscopic experiments. Francium is a highly radioactive metal, and since it exhibits a short half-life, it does not have more impact on the environment. Commercially, there are no uses for francium, due to its rarity and instability. It is used for research purposes only.

    Effects of francium on health

    Scientists know too little about francium to be aware of its health effects. As a radioactive element, however, it does pose a threat to human health.

    Effects of francium on the environment

    Due to its extremely short half-life only 22 minutes, it has no known biological role. It is toxic due to its radioactivity.

    Francium in the periodic table

    Atomic number (Z)87
    Groupgroup 1: H and alkali metals
    Periodperiod 7
    Block  s-block
    Electron configuration[Rn] 7s1
    Electrons per shell2, 8, 18, 32, 18, 8, 1

    Physical properties

    Physical properties
    Phase at STPsolid
    Melting point300 K ​(27 °C, ​81 °F)
    Boiling point950 K ​(677 °C, ​1251 °F)
    Density (near r.t.)2.48 g/cm3 (estimated)

    Vapor pressure (extrapolated)

    P (Pa)1101001 k10 k100 k
    at T (K)404454519608738946

    Atomic properties

    Atomic properties
    Oxidation states+1 (a strongly basic oxide)
    ElectronegativityPauling scale: >0.79
    Ionization energies

    1st: 393 kJ/mol

    Covalent radius260 pm (extrapolated)
    Van der Waals radius348 pm (extrapolated)

    Other properties

    Other properties
    Natural occurrencefrom decay
    Crystal structure​body-centered cubic (bcc)

    (extrapolated)
    Thermal conductivity15 W/(m·K) (extrapolated)
    Electrical resistivity3 µΩ·m (calculated)
    Magnetic orderingParamagnetic
    CAS Number7440-73-5

    History

    As early as the 1870s, the community of chemists believed that there must be an alkali-type metal with atomic number 876, below cesium in the periodic table. It was then known by the provisional name eka-cesium. Research teams were trying to find and isolate this missing element. At least four premature announcements of its discovery were made before it was actually discovered.

    Namingafter France, homeland of the discoverer
    Discovery and first isolationMarguerite Perey (1939)

    Main isotopes of francium

    It has 33 isotopes whose half-lives are known, with mass numbers 200 to 232. None are stable. 223Fr has the longest half-life at 21.8 minutes.

    Main isotopes of francium
    Iso­topeAbun­danceHalf-life (t1/2)Decay modePro­duct
    212Frsyn20.0 minβ+212Rn
    α208At
    221Frtrace4.8 minα217At
    222Frsyn14.2 minβ222Ra
    223Frtrace22.00 minβ223Ra
    α219At

    Periodic Table of Elements | Complete List of Chemical Elements by Group, Name, Symbol, Color and Type

    Periodic table elements
    Periodic Table of Elements | Complete List of Chemical Elements by Group, Name, Symbol, Color and Type

    Sources: PinterPandai, Live Science, Science Direct

    Photo credit: Wikimedia Commons

    Photo explanations: This sample of uraninite contains about 100,000 atoms (3.3×10−20 g) of francium-223 at any given time. Uraninite, formerly pitchblende, is a radioactive, uranium-rich mineral and ore with a chemical composition that is largely UO2, but due to oxidation the mineral typically contains variable proportions of U3O8. Additionally, due to radioactive decay, the ore also contains oxides of lead and trace amounts of helium. It may also contain thorium and rare earth elements.